Due to the most recent environmental requirements, wide desulfurization has become an increasingly important way to obtain ultraclean fuels for transportation of less than 15 ppmw of sulfur, such as diesel, gasoline, and jet fuel. as a result of the strict requirements for transportation fuels.
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Abstract. Flue gas desulfurization gypsum (FGDG) is an industrial byproduct generated during the flue gas desulfurization process in coalfired power plants. Due to its abundance, chemical and physical properties, FGDG has been used in several beneficial applications. However, during the past decade, the rate of beneficially used FGDG has ...
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The desulfurization process took place at a pH of 35, the coalparticle size was 7545 μm, the pulp density was 5%, the temperature was 35°C, and the incubation time was 8 h. Chemical studies also revealed a decrease in the ash content and an increase in the calorific value of coal from 6219 cal/g to 6406 and 6315 cal/g, which indicated ...
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What is desulphurization and how it is done? Desulfurization refers to the industrial process of removing sulfur from a mineral resource mixture such as crude oil. It predominantly involves a gaspurification industrial procedure used to remove hydrogen sulfide (H 2 S) and carbon dioxide (CO 2) from a given mineral resource.
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The process of bacterial coal desulfurization led to increase in calorific value showing advantage over conventional treatment methods. The optimum conditions of treatment time, pH, temperature, and coal pulp density for coal desulfurization by Aspergillus sp. was denoted as 8 days,, 35°C, and 5%, respectively ( Liu et al., 2017a ).
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Oxidation is the most widely used process for coal desulfurization [17, 2932] due to its ability to . remove the p yritic sulfur [33] and the macromolecular network [34].
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The occurrence of sulfur in coal direct liquefaction residue affects its further high quality and high value utilization. Electrochemical desulfurization is characterized by mild reaction conditions, simple operation, easy separation of sulfur conversion products and little influence on the properties of the liquefied residue. An anodic electrolytic oxidation desulphurization experiment was ...
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A process flow diagram for the HDS plant is shown in Fig. 1. Desulfurization reactions take place in fixed bed catalytic reactors (∆ R) where a minimum ratio H 2 /hydrocarbon must be ensured for catalyst maintenance reasons. Reactors are fed with a blend of fuels of different qualities. The hydrocarbon (HC) feed is mixed with the recycled H 2 stream (R) and with makeup H 2 from the network.
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Flue gas desulfurization systems (FGD) or scrubbers are devices capable of sulfur removal efficiencies between 50% to 98%. Typically the highest removal is achieved by wet scrubbers and the lowest by dry scrubbers. They are used in coalandoil fired combustion units including utility and industrial boilers, municipal and medical waste ...
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In 1978, Kirkbride proposed a desulfurization process: the raw coal will be properly pulverized, dried to remove free water, mixed with hydrogen and then treated by microwave radiation. H 2 reacts with S, N and O in coal producing H 2 S, NH 3 and water vapor thus achieving the purpose of desulfurization. The coal shall be as dry as possible ...
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Introduction. Flue gas desulfurized gypsum mainly comes from thermal power plants, smelters, and largeenterprise boilers, and contains industrial byproducts produced through a wet desulfurization combustion process, where SO 2 gas and lime slurry react under strong oxidation conditions. The main component of this gypsum is calcium sulfate dihydrate, which also contains calcium carbonate ...
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The FlueGas Desulfurization (FGD) process utilizes a set of technologies to remove sulfur dioxide (SO 2) from the flue gas emissions of coalfired power systems were developed as a response to the exhaust flue gases from fossil fuelburning plants, principally coalburning, that posed both an environmental and human health hazard.
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The flue gas desulfurization solids in the dry process (DFGDS) are the newly formed CaSO 4 and the unreacted excess of CaO. They are carried along with the coal FA out of the boiler, forming the end product (FA + DFGDS), which is highly alkaline due to the excess of CaO with respect to the initial SO 2 (Ca:S = ). Due to a low ...
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In this study, coal fly ash was functionalized, using a simple onestep process (loading with Al3+ and sulfonation), to yield a solid acid catalyst (S/AlCFA) with strong acid sites. The catalyst was then used to produce furfural from xylose in a biphasic system (H2O(NaCl)/tetrahydrofuran). The furfural yield reached 82% at 180 °C60 min with catalyst/xylose ratio of : (w/w).
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Flue gas desulphurisation (FGD) describes a process that removes sulphur dioxide (SO2) from a flue gas ( exhaust gas) stream. Sulphur dioxide is released to the atmosphere when fossil fuels are burnt and it is a leading contributor to acid rain. The FGD process has become critical to many industrial plants due to increasingly stringent ...
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The adsorption capacity of Sorbacals during the desulphurisation process of flue gases in the temperature range of 110130°C is discussed in detail in . ... J. Krátký, and L. Veverka, "The causation of high consumption of limestone in coal fluidized bed boiler desulfurization," CeramicsSilikáty, vol. 54, no. 1, pp. 8588, 2010.
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The addition of MPS or ZCS can help the materials stratify strictly according to the density to enhance the sorting function. The clean coal ash and sulfur content are reduced to % and %, while the combustible recovery and desulfurization efficiency are up to % and %, respectively, under the optimal condition.
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Wet flue gas desulfurization technology has become the most widely used desulphurization technology. The researchers have applied analytic hierarchy process to analyze three aspects of desulfurization system in power plant including technology, economy and sustainable development [1]. Abboud et al. [2] gave the detailed economic evaluation on
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As a typical industrial byproduct during the flue gas desulfurization process of coalfired, flue gas desulfurization ash (FGDA) with alkali mineral can facilitate the water damage resistance of asphalt mixtures. However, low density and high hydrophilic coefficient of FGDA limit its improvement effect.
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To understand its potential diffusion, we analysed a historical analogy: Flue Gas Desulfurization (FGD) in the global coal power market. Our findings challenge common patterns: diffusion of FGD is ...
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Process development of flue gas desulphurization wastewater treatment in coalfired power plants towards zero liquid discharge: Energetic, economic and environmental analyses. Xiaoqu Han Dan Zhang Junjie Yan Zhao Shuran Jiping Liu
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Hydrodesulfurization (HDS), also called hydrotreatment or hydrotreating, is a catalytic chemical process widely used to remove sulfur (S) from natural gas and from refined petroleum products, such as gasoline or petrol, jet fuel, kerosene, diesel fuel, and fuel oils. The purpose of removing the sulfur, and creating products such as ultralowsulfur diesel, is to reduce the sulfur dioxide (SO 2 ...
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The flue gas desulphurization can be done both by wet or dry process. The most widespread process is wet desulphurization of limestone or lime, accounting for about 85% of all desulphurization ...
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1000MW coalfired power plants using limestone gypsum wet desulphurization process are selected as the sample to . ... From the change of annual desulfurization cost of coalfired power plants (as .
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Coal combustion products (CCP) are fly ash, bottom ash (or boiler slag), and fluegas desulfurization gypsum. All have three fundamental properties: chemical composition, mineral composition, and particle size distribution. ... Coal combustion is a dirty process, releasing a range of pollutants including sulphur dioxide, nitrogen oxides, carbon ...
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Flue gas desulfurization gypsum (FGDG) is an industrial byproduct generated during the flue gas desulfurization process in coalfired power plants. Flue gas desulfurization systems have been used to limit the release of sulfur dioxide from coalfired power plants since the late 1960s, but in the past decade the production of FGDG has ...
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Fluegas desulfurization products and other air emissions controls. Ladwig, Blythe, in Coal Combustion Products (CCP's), 2017 Furnace sorbent injection systems. Another dry FGD technology that was developed in the 1970s and 1980s involves injection of limestone or hydrated lime into the upper furnace; this process is often called furnace sorbent injection, or FSI.
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A novel desulphurization process of coal water slurry via sodium metaborate electroreduction in the alkaline system article{Shen2012AND, title={A novel desulphurization process of coal water slurry via sodium metaborate electroreduction in the alkaline system}, author={Yafei Shen and Tonghua Sun and Jinping Jia}, journal={Fuel}, year={2012 ...
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